As moviegoers, we want the protagonists and antagonists to discover each other and end up together in a happily ever after. Nonetheless, there are occasions when the on-screen chemistry just doesn’t work, even if the performers and plot are both excellent. We’ve all been let down by a film’s romance because the two leads didn’t seem to have any chemistry. Whatever the case may be, these 10 on-screen couples just didn’t click despite their best efforts. From old favorites to summer blockbusters, these couples never managed to capture our attention with their passionate on-screen chemistry.

1. Anna and Alexei (Anna Karenina, 2012)

Anna Karenina, a married woman, starts an affair with Alexei Vronsky, a wealthy and charming cavalry commander. Although Anna first rejects his attempts, she gradually gives in to them as a result of her growing affection for him, beginning a passionate and deep love affair. Despite the challenges they encounter, Anna and Alexei have a strong bond and palpable chemistry throughout the plot, making for an engrossing and sad love story.

In actuality, the story is entirely different. The two celebrities were not romantically involved anyway. Both actors have talked openly about the value of keeping their personal lives and on-screen personas separate, and both are married to other people.

2. Aquaman and Mera (Aquaman, 2018)

One of the reasons why many people did not like a certain DC film was the lack of chemistry between the lead actors, notably the combination of Mera and Aquaman. A review of the movie by a critic and comments from viewers who saw it indicated dissatisfaction in the lack of genuine feelings and passion between the characters.

3. Daisy and Jay (The Great Gatsby, 2013)

In “The Great Gatsby” (2013), Daisy Buchanan and Jay Gatsby had a turbulent relationship filled with passion, longing, and tragedy. Despite their deep love, their relationship is difficult.

Daisy’s loyalty to her husband and desire for Gatsby leads to tragic consequences. Meanwhile, Gatsby’s idealized vision of Daisy creates an impossible standard that she cannot live up to, leading to a sense of distance and unfulfilled longing between them.

Carey Mulligan and Leonardo DiCaprio, however, did not have a romantic relationship outside of their respective roles in the movie.

4. Owen and Claire (Jurassic World, 2015)

The truth is still hidden behind the drama of their on-screen romance: Both actors are married to other people, and there is no evidence to suggest that they had a romantic relationship outside of their professional roles, and rumors of a love affair are hearsay.

5. Trinity and Neo (The Matrix, 1999–2003)

Because of a prophecy that claims Trinity would fall in love with “The One,” who will bring about the downfall of the Matrix, she is first captivated to Neo. Their relationship develops from a sense of duty to a deep and passionate love as they team up to fight the agents and robots. Trinity and Neo’s relationship is a major element in the “Matrix” movies, and their passionate love story gives the action-packed plot depth and emotional meaning.

Yet, in reality, they have never been romantically connected despite having professed their deep regard and admiration for one another as friends and coworkers. Moss and Reeves have their own families and are married to other people. Even though they are trained actors, their ability to portray love relationships on television may not accurately represent their relationships in real life.

6. Mary Jane and Peter (Spider-Man, 2002–2007)

The romance between Mary Jane Watson and Peter Parker plays a big role in the “Spider-Man” movie trilogy. Despite their difficulties, their love helps them get beyond the barriers they encounter separately and together. One of the most recognizable and enduring love tales in superhero movies is theirs.

However, Kirsten Dunst and Tobey Maguire, have talked about their close friendship and productive working relationship, but they have never been romantically linked.

In addition to “Spider-Man,” Dunst and Maguire have collaborated in a number of other projects, including “The Details” and “Pleasantville.” Both actors are talented performers. Although they have shown one other respect and appreciation as colleagues, they have kept their interactions exclusively business-related.

7. Ron and Hermione (Harry Potter and the Deathly Hallows, 2010)

The romantic relationship between Ron and Hermione in the “Harry Potter” movies is made up. The actors who played the characters, Rupert Grint and Emma Watson, are close friends in real life but have never been romantically linked. Despite their differences, they respect and help each other as friends and coworkers.

8. Daenerys and Jon (Game of Thrones, 2011–2019)

On-screen, Daenerys and Jon’s relationship in “Game of Thrones” starts as a political alliance and becomes romantic but ends tragically. How ever, Off-screen, Emilia Clarke and Kit Harington display having a close friendship but never had a romantic relationship.

9. Carl and Allison (Yes Man, 2008)

In the film “Yes Man,” Carl and Allison begin dating after meeting at a self-help conference. Their bond is presented as quirky and enjoyable, and the two characters go on impromptu trips together.
They do, however, mutually enjoy each other’s work and have a cordial working relationship despite never having an off-screen romantic relationship. In conclusion, their relationship off-screen differs from their connection on-screen because they are only colleagues who value one another’s talents.

10. Katniss and Peeta (The Hunger Games, 2012–2015)

The relationship between Katniss and Peeta develops from rivals in the Hunger Games to allies and then lovers. But their relationship only makes sense in the setting of the tale; it has no application in real life.

Josh Hutcherson and Jennifer Lawrence have consistently insisted that they are close friends and like working together. They have never been in a romantic relationship.